6533b85efe1ef96bd12bf4ec

RESEARCH PRODUCT

Electrochemistry of TiO2–iron hexacyanocobaltate composite electrodes

Mario BerrettoniMichela CiaboccoDelia Francesca Martino ChilluraMarco Giorgetti

subject

Composite materialPrussian blueMaterials scienceInorganic chemistryGeneral ChemistryElectrochemical depositionGlassy carbonCubic crystal systemCondensed Matter PhysicsElectrochemistryIndium tin oxideModified electrodeschemistry.chemical_compoundchemistryElectrodeGeneral Materials ScienceGraphiteIron hexacyanocobaltateFOIL methodSettore CHIM/02 - Chimica Fisica

description

Abstract In this paper we investigate the electrochemical behavior of iron hexacyanocobaltate (FeHCC) in comparison to the cobalt hexacyanoferrate (CoHCF). The best results were achieved on electrochemical synthesized film of FeHCC on the TiO2 modified electrodes. The chemical and physical characterizations confirm the formation of the FeHCC with the classical cubic crystal structure of the Prussian blue analogs, with cell parameter a very close to 10 A, as well as the formation of micro aggregates of TiO2 covered by FeHCC. The synthesis was performed on various substrates such as glassy carbon (GC), graphite foil (GF) and indium tin oxide (ITO) in order to develop new technological applications.

yearjournalcountryeditionlanguage
2014-06-01
10.1016/j.ssi.2014.02.019http://hdl.handle.net/11585/364517