Elektronisko pāreju uz zemāko tripleta stāvokli a3Sigma(+) reģistrācija un analīze RbCs un KCs molekulās

6533b85efe1ef96bd12c012a

RESEARCH PRODUCT

Elektronisko pāreju uz zemāko tripleta stāvokli a3Sigma(+) reģistrācija un analīze RbCs un KCs molekulās

Valts Krūmiņš

subject

c3S+ stāvoklis A~b komplekss Fizika KCs molekula RbCs molekula a3S+ stāvoklis

description

Maģistra darbā tika pētītas pārejas no sajauktiem ierosinātiem elektroniskiem stāvokļiem uz a3Σ+ stāvokli RbCs un KCs molekulās. Pielietojot lāzeru inducētās fluorescences (LIF) augstas izšķirtspējas Furjē transformāciju spektroskopiju, RbCs molekulā ir novērotas un analizētas pārejas no A1Σ+~b3Π kompleksa uz a3Σ+, kas ļauj pārliecināties par aprēķināto A~b kompleksa viļņu funkciju precizitāti, kā arī pārbaudīt pārejas dipola momenta funkciju aprēķinu korektumu. KCs molekulā tika novērotas LIF pārejas no c3Σ+ stāvokļa uz a3Σ+ stāvokli. Tas ļāva noteikt c3Σ+ stāvokļa līmeņu enerģijas, kas nepieciešams šī stāvokļa potenciāla iegūšanai. Pāreja c3Σ+ → a3Σ+ tika izmantota arī spektru reģistrācijai uz a3Σ+ stāvokļa atgrūšanās daļu virs disociācijas robežas, kas dod informāciju par šī stāvokļa potenciālu šajā diapazonā.

year	journal	country	edition	language
2021-01-01

https://dspace.lu.lv/dspace/handle/7/55998

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