6533b85efe1ef96bd12c027a

RESEARCH PRODUCT

IONIC LIQUIDS MODIFIED CATALYSTS: SYNTHESIS, IMMOBILIZATION AND USES.

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description

Synthesis, catalytic activity and recovery of Ionic liquid modified and un-modified catalysts have mainly been focused in this thesis. Particularly, our attention has been given to 2,2,6,6-Tetramethyl-piperidine-N-oxyl (TEMPO) catalyst for its unique redox behavior in alcohol oxidation to carbonyl compounds. In order to tag appropriate number of IL moieties, [60]Fullerene as well as benzylic linker units were employed as a molecular support. However, covalently supported catalysts were recovered by a short silica pad while, ionic liquid-tagged TEMPO catalysts were recovered by a non-covalent “Release and Catch” approach using silica grafted polymeric multilayered covalently supported ionic liquid phase (mlc-SILP) material. Eventually, substrate scope of successfully recovered catalysts was tested by using a series of different primary and secondary alcohols and which were quantitatively converted with the aid of less amount of the catalyst about 0.05-10 mol%.