6533b85efe1ef96bd12c063e
RESEARCH PRODUCT
N-{(Z)-2-[1-(Triisopropylsilyl)-1H-indol-3-yl]-2-(triisopropylsilyloxy)vinyl}-2-(3,4,5-trimethoxyphenyl)acetamide
Roland SeligDieter SchollmeyerChristian PeiferStefan Laufersubject
chemistry.chemical_classificationchemistry.chemical_compoundDouble bondchemistrySilylationSide productGeneral Materials ScienceGeneral ChemistryCondensed Matter PhysicsProtecting groupMedicinal chemistryAcetamidedescription
The molecular structure of the title compound, C39H62N2O5Si2, obtained as an unexpected side product, was determined in the course of our studies on the synthesis of N-triisopropyl-1H-indol-3-yl derivatives. Interestingly, although the triisopropylsilyl group was intended as a temporary protecting group, the compound comprises a remarkably stable N—Si bond. The vinyl C=C double bond possesses a Z configuration.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-02-14 | Acta Crystallographica Section E Structure Reports Online |