6533b85efe1ef96bd12c0653
RESEARCH PRODUCT
Evidence for the formation of sodium hassate(VIII)
Bernhard KuczewskiMatthias SchädelAndré Von ZweidorfU. RiethGert LangrockNorbert TrautmannW. BrüchleStephan BürgerH. HummrichK. TsukadaJens Volker KratzNorbert Wiehlsubject
chemistry.chemical_compoundAqueous solutionchemistrySiliconSodiumInorganic chemistryOxidechemistry.chemical_elementPartial pressurePhysical and Theoretical ChemistryLayer (electronics)Deposition (chemistry)Hassiumdescription
SummaryHassium, element 108, was produced in the fusion reaction between26Mg and248Cm. The hassium recoils were oxidizedin-situto a highly volatile oxide, presumably HsO4, and were transported in a mixture of He and O2to a deposition and detection system. The latter consisted of 16 silicon PIN-photodiodes facing a layer of NaOH, which served, in the presence of a certain partial pressure of water in the transport gas, as reactive surface for the deposition of the volatile tetroxides. Six correlated α-decay chains of Hs were detected in the first 5 detectors centred around detection position 3. In analogy to OsO4, which forms Na2[OsO4(OH)2], an osmate(VIII), with aqueous NaOH, HsO4presumably was deposited as Na2[HsO4(OH)2], a hassate(VIII).
year | journal | country | edition | language |
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2004-12-01 | Radiochimica Acta |