A hexaicosametallic copper(ii) phosphonate

6533b85efe1ef96bd12c0715

RESEARCH PRODUCT

A hexaicosametallic copper(ii) phosphonate

Ramakirushnan Suriya Narayanan Emilio Pardo Franscesc Lloret Vadapalli Chandrasekhar Vadapalli Chandrasekhar Ray J. Butcher Dipankar Sahoo

subject

Inorganic Chemistry chemistry.chemical_compound chemistry Transition metal Inorganic chemistry chemistry.chemical_element Normal solution Phosphonate Copper

description

Structure and characterization of [Cu26{2,3,5,6-(Me)4C6H-CH2-PO3}18(μ2-OH)4(μ3-OH)6(μ4-Cl)6(μ-OH2)2(OH2)2(MeCN)4]·6MeCN·15H2O (1) is reported. Complex 1 is the largest discrete molecular homometallic transition metal phosphonate assembly. Remarkably, this gigantic molecular phosphonate has been prepared at room temperature using a normal solution synthetic method.

year	journal	country	edition	language
2013-05-11	Dalton Transactions

https://doi.org/10.1039/c3dt00103b

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