Selective formation of a unique diphosphonium-diphosphine from a tetraphosphine double protonation induced by zirconium salts

6533b85efe1ef96bd12c071e

RESEARCH PRODUCT

Selective formation of a unique diphosphonium-diphosphine from a tetraphosphine double protonation induced by zirconium salts

Philippe Meunier Nikolay V. Vologdin Ali Jahel Jean-cyrille Hierso Hélène Cattey Philippe Richard Nadine Pirio

subject

crystal structure Zirconium Selective reaction 010405 organic chemistry Chemistry protonation Inorganic chemistry [ CHIM.COOR ] Chemical Sciences/Coordination chemistry zirconium Ionic bonding chemistry.chemical_element Protonation phosphonium 010402 general chemistry 01 natural sciences ferrocenyl 0104 chemical sciences 3. Good health Inorganic Chemistry Polymer chemistry polyphosphine [CHIM.COOR]Chemical Sciences/Coordination chemistry ComputingMilieux_MISCELLANEOUS

description

A mixed ferrocenyl diphosphonium-diphosphine cation, associated with two [ZrCl(5).thf](-) anions, is obtained from a ferrocenyl tetraphosphine, as a unique didentate ionic metalloligand in a perfectly selective reaction induced by ZrCl(4) in THF.

year	journal	country	edition	language
2008-08-07	Dalton Transactions

https://doi.org/10.1039/b809244n

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