Light Induced C-C Coupling of 2-Chlorobenzazoles with Carbamates, Alcohols, and Ethers.

6533b85ffe1ef96bd12c126c

RESEARCH PRODUCT

Light Induced C-C Coupling of 2-Chlorobenzazoles with Carbamates, Alcohols, and Ethers.

subject

010405 organic chemistry Organic Chemistry 010402 general chemistry 01 natural sciences Coupling reaction 0104 chemical sciences chemistry.chemical_compound C c coupling chemistry Reagent Light induced Benzophenone Organic chemistry Acetonitrile Sodium acetate

description

A light induced, transition-metal-free C-C coupling reaction of 2-chlorobenzazoles with aliphatic carbamates, alcohols, and ethers is presented. Inexpensive reagents, namely sodium acetate, benzophenone, water, and acetonitrile, are employed in a simple reaction protocol using a cheap and widely available 25 W energy saving UV-A lamp at ambient temperature.

year	journal	country	edition	language
2016-04-30	The Journal of organic chemistry

10.1021/acs.joc.6b00715 https://pubmed.ncbi.nlm.nih.gov/27128627

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