6533b85ffe1ef96bd12c139f
RESEARCH PRODUCT
Multielectron transfer in a dicopper(II) anthraquinophane.
Joan CanoMiguel JulveDonatella ArmentanoFrancesc LloretRafael Ruiz-garcíaMaría CastellanoGiovanni De MunnoYves Journauxsubject
Metals and Alloyschemistry.chemical_elementBridging ligandGeneral ChemistryPhotochemistryAnthraquinoneCopperRedoxCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographychemistry.chemical_compoundchemistryAlkane stereochemistryMaterials ChemistryCeramics and Compositesdescription
The new dinuclear copper(II) metallacyclophane with the non-innocent N,N'-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled Cu(II) ions and two-electron reduction of the anthraquinone spacers in a π-stacked anti conformation.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-03-22 | Chemical communications (Cambridge, England) |