Crystal structure of bis(μ2-methanolato-κO:κO)hexamethylbis(μ2-triphenylacetato-κO:κO′)bis(μ2-triphenylacetato-κ2O,O′:κO)dialuminiumdilanthanum toluene tetrasolvate

6533b85ffe1ef96bd12c1779

RESEARCH PRODUCT

Crystal structure of bis(μ2-methanolato-κO:κO)hexamethylbis(μ2-triphenylacetato-κO:κO′)bis(μ2-triphenylacetato-κ2O,O′:κO)dialuminiumdilanthanum toluene tetrasolvate

Alexander A. Vinogradov Dmitrii M. Roitershtein Mikhail E. Minyaev Konstantin A. Lyssenko Ilya E. Nifant’ev

subject

triphenylacetate lcsh:Chemistry crystal structure lanthanum lcsh:QD1-999 aluminium triphenylacetate π-complex Research Communications coordination compound

description

The complex [{La(Ph3CCOO)2(Me3AlOMe)}2] has an La2(μ-OCO)4 core, contains the carboxylate ligands in μ2-κ1 O:κ1 O′ bridging and μ2-κ2 O,O′:κ1 O semi-bridging coordination modes, and displays La—C interactions with the π-system of a phenyl ring.

year	journal	country	edition	language
2018-11-01	Acta Crystallographica Section E: Crystallographic Communications

10.1107/s2056989018015876 http://scripts.iucr.org/cgi-bin/paper?S2056989018015876

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