6533b85ffe1ef96bd12c1967

RESEARCH PRODUCT

Investigations on organoantimony compounds

J. G. NoltesRenato BarbieriEleonora RivarolaH. A. MeinemaNuccio BertazziFrancesca Di Bianca

subject

StereochemistryLigandOrganic Chemistrychemistry.chemical_elementZonal and meridionalBiochemistryNmr dataInorganic ChemistryCrystallographyOctahedronAntimonychemistryMaterials ChemistryPhysical and Theoretical Chemistry

description

Abstract Diorganoantimony(V) complexes of the type R 2 SbClTrid (R = Me, Ph) containing dianionic, potentially tridentate Schiff-base ligands with ONO donor atoms (Trid 2− ) have been prepared and characterized. IR and NMR data suggest an octahedral coordination environment for the antimony atom with meridional arrangement of the ONO ligand atoms and a linear CSbC skeleton.

https://doi.org/10.1016/s0022-328x(00)91542-0