6533b85ffe1ef96bd12c1c22
RESEARCH PRODUCT
Intercalation effects in LDPE/o-Montmorillonites nanocomposites
Aldo PriolaSilvia Maria RonchettiN. LakFrancesco Paolo La MantiaGiulio MalucelliNadka Tzankova Dintchevasubject
NanocompositeMorphology (linguistics)Materials sciencePolymers and PlasticsOrganic ChemistryIntercalation (chemistry)General Physics and AstronomyLow-density polyethylenechemistry.chemical_compoundMontmorillonitechemistryRheologyPolymer chemistryMaterials ChemistryThermal stabilityPolymer blendNuclear chemistrydescription
Abstract Typical montmorillonite clays (Cloisite ® Na + , Cloisite ® 30B) were modified by treatment with octadecyl ammonium chloride (ODC) and successive additions of octadecylamine (ODA). XRD analyses of the modified clays indicated an increase of the basal spacing of the (0 0 1) planes depending on the ODC or ODA additions. Nanocomposites were prepared by dispersing the modified clays (3% w/w concentration) in LDPE, using a Brabender mixer. XRD measurements of the obtained products indicated in some cases the achievement of intercalation effects, which were confirmed by TEM analysis. Some thermal, mechanical, dynamic-mechanical and rheological properties were evaluated and correlated to the degree of intercalation.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-02-01 |