6533b85ffe1ef96bd12c1cd1

RESEARCH PRODUCT

Crystal structures of three mercury(II) complexes [HgCl2L] where L is a bidentate chiral imine ligand

Guadalupe HernándezSylvain BernèsRené GutiérrezAlejandro RuizGloria E. MorenoOscar Portillo

subject

crystal structureSchiff baseDenticitymercuryStereochemistryIminechemistry.chemical_elementGeneral ChemistryCrystal structureLarge rangeBite angleCondensed Matter PhysicsResearch CommunicationsMercury (element)lcsh:Chemistrychemistry.chemical_compoundCrystallographySchiff basechemistrylcsh:QD1-999General Materials Sciencedisphenoidal geometryCoordination geometry

description

Three complexes synthesized by coordination of chiral imines to HgCl2 have been characterized, in which the tetra­hedral HgII centre has a geometry strongly distorted towards the disphenoidal geometry.

10.1107/s2056989015020368http://scripts.iucr.org/cgi-bin/paper?S2056989015020368