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RESEARCH PRODUCT
Thermodynamics of electrokinetic processes—I. Formulations
Vicente CompañJavier GarridoSalvador MafeVicente M. Aguilellasubject
Electrokinetic phenomenaCharacter (mathematics)Phenomenological equationsChemistryGeneral Chemical EngineeringElectrochemistryApplied mathematicsMineralogydescription
Abstract The phenomenological equations of electrokinetic processes are studied according to five different formulations. Transformation matrices with Haase's formulation are given. A study of the measurable character of fluxes, forces and phenomenological coefficients in those formulations is also made. The extrinsic character, if so, of the formulations is examined and a general definition of formulations established only for binary solutions is given. Finally, a review of the literature is included, aiming to clarify the possible misunderstandings arising from the application of these five formulations.
year | journal | country | edition | language |
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1990-04-01 | Electrochimica Acta |