6533b85ffe1ef96bd12c2517
RESEARCH PRODUCT
The decomposition of 1-phenyl-3-chloro-nortricyclene and 1-phenylnortricyclene on reduction in 1,2-dimethoxyethane. The EPR spectra of the radical ions
Jaakko PaasivirtaRaili VesterinenJorma ElorantaReijo Moilanensubject
BiphenylChemistryPotassiumchemistry.chemical_elementGeneral ChemistryPhotochemistryDecompositionDimethoxyethanelaw.inventionIonchemistry.chemical_compoundRadical ionlawGeneral Materials ScienceElectron paramagnetic resonanceNaphthalenedescription
Radical anions of 1-phenyl-3-chloronortricyclene and 1-phenylnortricyclene were produced by reduction with potassium in 1,2-dimethoxyethane under a high vacuum. The initially formed radical anion of 1-phenyl-3-chloronortricyclene was very unstable, and decomposed finally to the anions of naphthalene and biphenyl. The only product of the reduction of 1-phenylnortricyclene was the biphenyl anion. The EPR spectra of the reaction mixtures were measured at temperatures from —80°C to room temperature.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1972-08-01 | Organic Magnetic Resonance |