6533b85ffe1ef96bd12c2536

RESEARCH PRODUCT

Synthesis and stereochemistry of some new derivatives of cis-dihydropinol

Zbigniew CiunikAlicja. SiemieniukStanisław LochyńskiCzesław WawrzeńczykKrzysztof. PiątkowskiBożena Frąckowiak-wojtasek

subject

Inorganic Chemistrychemistry.chemical_compoundCyclohexanechemistryGroup (periodic table)StereochemistryOrganic ChemistryPhysical and Theoretical ChemistryRing (chemistry)CatalysisStereocenter

description

Abstract The synthesis of four new derivatives of cis-hydroxy-cis-dihydropinol with allyl-, epoxyalkyl-, hydroxyalkyl- and ketoalkyl-groups substituted on the cyclohexane ring is presented. The cis-orientation of hydroxyl group at C-2 and the configuration of all stereogenic centers is confirmed by X-ray crystallography.

https://doi.org/10.1016/s0957-4166(99)00056-7