6533b85ffe1ef96bd12c2934
RESEARCH PRODUCT
Hydrogen activation with perfluorinated organoboranes: 1,2,3- tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene
Adrian Y. HoughtonVirve KarttunenWarren E. PiersHeikki Tuononensubject
fluorattu boraindeeniperfluorinated boraindenevedyn aktivointihydrogen activationorganoboron compoundsorganoboraanitdescription
The perfluorinated boraindene 3 was synthesized and fully characterized. Both computational and crystallographic data show that 3 is antiaromatic. Compound 3 was shown to react reversibly with H2 and to catalyse the hydrogenation of cyclohexene. The mechanism of catalysis was probed experimentally and computationally. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-01-01 |