Electrochemical Quartz Crystal Microbalance Study of Copper Electrochemical Reaction in Acid Medium Containing Chlorides

6533b860fe1ef96bd12c2e05

RESEARCH PRODUCT

Electrochemical Quartz Crystal Microbalance Study of Copper Electrochemical Reaction in Acid Medium Containing Chlorides

Claude Gabrielli José Juan García-jareño David Giménez-romero Francisco Vicente Hubert Perrot

subject

Reaction mechanism Renewable Energy Sustainability and the Environment Chemistry Inorganic chemistry chemistry.chemical_element Quartz crystal microbalance Condensed Matter Physics Electrochemistry Copper Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ion Metal visual_art Materials Chemistry Electrochemistry visual_art.visual_art_medium Gravimetric analysis Cyclic voltammetry

description

Copper electrodissolution and electrodeposition were studied by means of gravimetric quartz crystal microbalance and electric cyclic voltammetry combined measurements. Relevant information on the mechanism of these electrochemical processes is provided by the analysis of experimental data and particularly of the mass change per charge unit. The copper electrodeposition and electrodissolution take place by means of two consecutive monoelectronic transfers where the anion participation in the reaction mechanism is specified. Besides, it is proved that the presence of molecular oxygen in the solution contributes to the formation of a passive layer on the surface of the metallic copper deposit.

year	journal	country	edition	language
2006-01-01	Journal of The Electrochemical Society

https://doi.org/10.1149/1.2181315

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