6533b860fe1ef96bd12c2e2b

RESEARCH PRODUCT

ChemInform Abstract: New Route to Herbertanes via a Suzuki Cross-Coupling Reaction: Synthesis of Herbertenediol.

Consuelo AgullóRemedios H. PerniAna C. CuñatAntonio AbadDiego Jimenez

subject

Terpenechemistry.chemical_compoundChemistryStereochemistryGroup (periodic table)General MedicineSesquiterpeneHerbertenediolCoupling reaction

description

Abstract The synthesis of herbertenediol, a relevant member of the herbertane-type sesquiterpene family, is described. The synthesis is based on a new general approach to this group of sesquiterpenes where the herbertane skeleton is constructed using a Suzuki cross-coupling reaction and a [2,3]-sigmatropic Still–Wittig rearrangement as key synthetic steps.

yearjournalcountryeditionlanguage
2010-05-22ChemInform
https://doi.org/10.1002/chin.200212225