6533b860fe1ef96bd12c312c
RESEARCH PRODUCT
The correlation between electrochemical impedance spectra and voltammograms of PB films in aqueous NH4Cl and CsCl
Francisco VicenteJ. Navarro-laboulaisJosé Juan García-jareñoA. Sanmatı́assubject
chemistry.chemical_classificationPrussian blueAqueous solutionSupporting electrolyteGeneral Chemical EngineeringDiffusionInorganic chemistryAnalytical chemistrySalt (chemistry)Dielectric spectroscopychemistry.chemical_compoundchemistryElectrochemical impedance spectraElectrochemistryCounteriondescription
Abstract Voltammetric curves of reduction of Prussian Blue Films to the Everitt’s Salt form and oxidation to the Prussian Yellow form show important differences depending on the supporting electrolyte countercation. The rate of the overall electron-hopping depends on the countercation. Apparent diffusion coefficients are evaluated from impedance spectra at different stabilization potentials. The dependence of the apparent diffusion coefficients on the stabilization potential can help understand the dependence of the voltammograms shape on the countercation nature.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1998-04-01 |