6533b860fe1ef96bd12c3142

RESEARCH PRODUCT

Chlorido(dimethyl sulfoxide)(pyridine-2-thiolato N-oxide-κ2S,O)platinum(II)

P. Selvarathy GraceB. Ravindran Durai NayagamDieter SchollmeyerSamuel Robinson Jebas

subject

chemistry.chemical_classificationChemistryHydrogen bondLigandDimethyl sulfoxideOxidechemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsBioinformaticsMedicinal chemistryIonlcsh:Chemistrychemistry.chemical_compoundlcsh:QD1-999PyridineThiolGeneral Materials SciencePlatinum

description

The asymmetric unit of the title compound, [Pt(C5H4NOS)Cl(C2H6OS)], contains two independent complex molecules having similar geometries. Each PtII atom is four-coordinated in a distorted square-planar geometry by S and O atoms of one pyridine N-oxide ligand, the S atom of one dimethyl sulfoxide molecule and one terminal Cl− ion. The molecules are linked into a three-dimensional framework by C—H...O and C—H...Cl hydrogen bonds.

10.1107/s1600536808019041http://scripts.iucr.org/cgi-bin/paper?S1600536808019041