6533b860fe1ef96bd12c326b

RESEARCH PRODUCT

Fragmentations and reactions of the organophosphate insecticide Diazinon and its oxygen analog Diazoxon studied by electrospray ionization ion trap mass spectrometry

Christopher M. TimperleyJ. MurrellP. WattsJ. D. BarrM. BirdFrancesco FerranteJ. L. MundyA. J. Bell

subject

InsecticidesSpectrometry Mass Electrospray IonizationElectrosprayDiazinonChromatographyChemistryorganophosphateElectrospray ionizationMass spectrometryPhotochemistryIonchemistry.chemical_compoundOrganophosphorus CompoundsFragmentation (mass spectrometry)FragmentationStructural BiologyDiazinonProton affinityIon trapSpectroscopyEnvironmental Monitoring

description

The fragmentations and reactions of Diazinon and related compounds have been studied by electrospray ionization ion trap mass spectrometry. Several novel fragmentation and rearrangements have been observed, including an intramolecular thiono-thiolo rearrangement. The stability, in the gas-phase, of the protomers of 2-isopropyl-4-methyl-6-pyrimidinol has been demonstrated. The complexity of the gas phase ion processes observed suggest that, at present, caution Should be exercised in using this approach for the analysis of environmental and other samples until our understanding of these processes increases considerably. (J Am Soc Mass Spectrom 2005, 16, 515-523) (c) 2005 American Society for Mass Spectrometry

yearjournalcountryeditionlanguage
2005-04-01Journal of the American Society for Mass Spectrometry
https://doi.org/10.1016/j.jasms.2004.12.013