6533b860fe1ef96bd12c3b1a

RESEARCH PRODUCT

Biopolymeric bilayer films produced by co-extrusion film blowing

Luigi BottaFiorenza SuteraRoberto Scaffaro

subject

Hydrolytic degradationMaterials sciencePolymers and Plastics02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesContact anglechemistry.chemical_compoundMonolayerPolymer chemistrychemistry.chemical_classificationpHBilayerOrganic ChemistryPolymer021001 nanoscience & nanotechnology0104 chemical sciencesLactic acidchemistryChemical engineeringBilayer filmengineeringBiodegradablePLADegradation (geology)BiopolymerElongation0210 nano-technologyMelt processing

description

Abstract Biodegradable packaging promises a more environmentally friendly future. Nevertheless, a single biopolymer often lacks of some important properties. In order to contribute to this challenge, biodegradable bilayer films from poly(lactic acid) (PLA) and MaterBi® were prepared in this work and compared with monolayer films obtained with both the polymers. The prepared films were fully characterized through morphological, mechanical, thermal, chemical, optical and water contact angle analyses. Furthermore, the hydrolytic degradation of monolayer and bilayer films was studied by performing tests at three different pH. The morphological analysis revealed that PLA/MaterBi bilayer films show good interfacial adhesion, even under the stretching in the mechanical tests. The bilayer film showed a higher stiffness than that of MaterBi and a larger elongation at break in comparison with PLA. The degradation tests revealed that weight loss is faster at pH 10 for all the systems and that at this pH the bilayer film show the highest degradation rate.

https://doi.org/10.1016/j.polymertesting.2017.11.010