6533b860fe1ef96bd12c40b3

RESEARCH PRODUCT

Interactions and resonances in quantum systems

Guillaume Saget

subject

Adjoint opérateur[PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph][ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph]General Heun functionCoordonnées internesRésonance p:qInternal coordinates[PHYS.QPHY] Physics [physics]/Quantum Physics [quant-ph]P:q resonanceOpérateur adjointÉquation de Heun

description

This thesis book is concerned with the interactions and resonances in quantum systems and is subdivided into three thematics. First, our work is aimed at constructing in the local limit a systematic method for a normalized vibrational Hamiltonian for a strongly excited n-degree-of-freedom molecular system from the generators of the Lie algebra, the algebra of the invariant polynomials built in classical mechanics from the the kernel of the adjoint operator adH0 . We present both the method of construction in case of absence and in case of a p : q resonance system with n degrees of freedom. Application to the non-linear triatomic molecule ClOH is then given.On the other hand, by using the LTPA Algorithm, we realize normalisation of linear triatomic molecules and we compare in case of the CO2 molecule our results to those of authors who used to another approaches. Then, we are dealing with the Fermi interaction in order to show analogously to the building of Hamiltonians of non-linear molecules AB2, that this interaction is able to describe the transition of a atomic Bose-Einstein condensate (BEC) to a molecular one.Finally, in the last chapter, we explore the non-adiabatic dynamics of a two-state system subject to excitation by a specific constant-amplitude periodic level-crossing model and we show that the evolution of the probability amplitudes of states is deduced from the Heun equation for a particular class of solutions. We also highlight three different behaviors for the detuning : non-crossing, crossing and level-glancing. For these two last behaviors, a 1 : 1 resonance occurs periodically between the system and the field.

https://tel.archives-ouvertes.fr/tel-01798993/document