Optically detected magnetic resonance investigation of a luminescent oxygen–vacancy complex in Mn-doped LiBaF3

6533b861fe1ef96bd12c4c5c

RESEARCH PRODUCT

Optically detected magnetic resonance investigation of a luminescent oxygen–vacancy complex in Mn-doped LiBaF3

Stefan Schweizer Uldis Rogulis B. Henke

subject

Photoluminescence Chemistry Doping Condensed Matter Physics law.invention Crystallography Nuclear magnetic resonance Impurity law Vacancy defect Excited state General Materials Science Triplet state Luminescence Electron paramagnetic resonance

description

The structure of an oxygen-related luminescence centre in manganese-doped LiBaF 3 was investigated by means of photoluminescence (PL) and PL-detected electron paramagnetic resonance. At 20 K an oxygen-related complex shows two luminescence bands peaking at about 430 and 475 nm, when excited at 220 nm. These bands can be attributed to an excited triplet state (S = 1) of an oxygen-vacancy complex with the z axis of the fine structure tensor parallel to the (110) direction. This complex is believed to be next to a Mn 2+ impurity on a Ba 2+ site and can be described as an oxygen on a fluorine lattice site with a nearest fluorine vacancy along the (110) direction.

year	journal	country	edition	language
2006-01-17	Journal of Physics: Condensed Matter

https://doi.org/10.1088/0953-8984/18/5/010

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