ChemInform Abstract: Photochemical Cyclization of Some Aldehyde Thiosemicarbazones.

6533b861fe1ef96bd12c4cc4

RESEARCH PRODUCT

ChemInform Abstract: Photochemical Cyclization of Some Aldehyde Thiosemicarbazones.

Michelangelo Gruttadauria Francesco Buccheri Giuseppe Cusmano Silvestre Buscemi Giuseppe Werber Renato Noto

subject

chemistry.chemical_classification chemistry.chemical_compound chemistry Organic chemistry General Medicine Methanol Ring (chemistry)Photochemistry Aldehyde

description

The photochemical behaviour of some substituted aldehyde thiosemicarbazones 1a-k has been investigated in methanol at 254 nm. Thiosemicarbazones of glyoxil methyl ester 1a-f cyclized to furnish the 3-thioxo- 1,2,4-triazin-5-one 2 ring system. The remaining thiosemicarbazones 1g-j gave 1,2,4-triazoline 4 derivatives.

year	journal	country	edition	language
2010-08-21	ChemInform

https://doi.org/10.1002/chin.199232176

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