Solution Properties of Polyelectrolytes. VI. Secondary Effects in Aqueous Size-Exclusion Chromatography

6533b861fe1ef96bd12c4d49

RESEARCH PRODUCT

Solution Properties of Polyelectrolytes. VI. Secondary Effects in Aqueous Size-Exclusion Chromatography

Rosa García Vicente Soria Maria Jesus Parets Agustín Campos

subject

Chromatography Aqueous solution Volume (thermodynamics)Ionic strength Chemistry Sodium Size-exclusion chromatography Molecular Medicine chemistry.chemical_element Electrolyte Polyelectrolyte

description

Abstract An independent analysis of different operational variables in aqueous size exclusion chromatography of poly electrolytes has been carried out using a silica-based support. The effect of polyion concentration, pH and ionic strength on sodium polystyrenesulfonate calibration plots has been investigated. Finally, a novel semi-empirical model has been developed from thermodynamic considerations which relates the support effective pore volume to the polyelectrolyte molecular weight and qualitatively describes secondary effects.

year	journal	country	edition	language
1990-06-01	Journal of Liquid Chromatography

https://doi.org/10.1080/01483919008048992

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