6533b861fe1ef96bd12c4e0a

RESEARCH PRODUCT

Mn(IV) and Co(III)-complexes of –OH-rich ligands possessing O2N, O3N and O4N cores: syntheses, characterization and crystal structures

Philippe GuionneauErkki KolehmainenChebrolu P. RaoPauli SaarenketoKari RissanenMishtu Dey

subject

Manganese(IV) complexCrystal structure010402 general chemistry01 natural sciencesHydrogen bondsInorganic ChemistryMetalMagnetic momentMaterials ChemistryPhysical and Theoretical ChemistryCobalt(III) complexCoordination geometryMagnetic moment010405 organic chemistryHydrogen bondChemistryCrystal structure[CHIM.MATE]Chemical Sciences/Material chemistry0104 chemical sciences3. Good healthCharacterization (materials science)CrystallographyOctahedronvisual_artvisual_art.visual_art_mediumSingle crystal

description

Mn(IV) and Co(III) complexes of tridentate –OH–rich ligands possessing O2N, O3N and O4N donor sets were synthesized, characterized and their structures were established by single crystal X-ray diffraction, where the binding core is O4N2. In the structurally characterized complexes, the coordination geometry about the metal ion was found to be distorted octahedral.

10.1016/j.poly.2003.09.015https://hal.archives-ouvertes.fr/hal-00172972