ChemInform Abstract: Diastereoselective Intramolecular Additions of Allyl- and Propargylsilanes to Iminium Ions: Synthesis of Cyclic and Bicyclic Quaternary Amino Acids.

6533b861fe1ef96bd12c5774

RESEARCH PRODUCT

ChemInform Abstract: Diastereoselective Intramolecular Additions of Allyl- and Propargylsilanes to Iminium Ions: Synthesis of Cyclic and Bicyclic Quaternary Amino Acids.

Natalia Mateu Jose Luis Acena Santos Fustero Antonio Simón-fuentes

subject

chemistry.chemical_classification Allylic rearrangement chemistry Bicyclic molecule Intramolecular force Iminium General Medicine Medicinal chemistry Ion Amino acid

description

Cyclization of the chiral imino lactones with allylic or propargylic groups required acidic conditions to afford spirocyclic (II) or (XII).

year	journal	country	edition	language
2010-10-25	ChemInform

https://doi.org/10.1002/chin.201046184

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