6533b862fe1ef96bd12c63fe

RESEARCH PRODUCT

cis-Bis(2-sulfidopyridine N-oxide)platinum(II).

B. Ravindran Durai NayagamSamuel Robinson JebasDieter Schollmeyer

subject

Metal-Organic PapersCrystallographyChemistryOxidechemistry.chemical_elementGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsBioinformaticsPlanarity testingchemistry.chemical_compoundCrystallographyQD901-999PyridineGeneral Materials SciencePlatinumCis–trans isomerismCoordination geometry

description

In the crystal structure of the title complex, [Pt(C5H4NOS)2], the Pt atom is coordinated by two O atoms and two S atoms in a cis configuration, forming a distorted square-planar coordination geometry. The molecule exhibits pseudo-C2v symmetry and is essentially planar, with a maximum deviation from planarity of 0.0124 (2) Å. The dihedral angle between the two pyridine rings is 5.85 (2)°.

10.1107/s1600536808002006https://pubmed.ncbi.nlm.nih.gov/21201369