6533b862fe1ef96bd12c734c
RESEARCH PRODUCT
Chimie de coordination du phosphore aux métaux du groupe 11 : progrès en catalyse de couplage C-N au Cu(I) et nouveaux complexes polyphosphines de l'Au(I)
Vincent Rampazzisubject
Polyphosphine ferrocéniqueAurophilicity[CHIM.ORGA]Chemical Sciences/Organic chemistryOrHybrid ligandLigand hybrideCatalyse[CHIM.ORGA] Chemical Sciences/Organic chemistryFerrocenic polyphosphineCatalysisChimie de coordinationCoordination chemistry[ CHIM.ORGA ] Chemical Sciences/Organic chemistryCuivreGoldAurophilieCopperdescription
Nowadays, sustainable development encourages chemists to develop new economic and ecologic synthesis, because natural ressources are reducing. Most exploited ressources are gas and petroleum, but precious metals are also essential. This thesis is focusing on the enhancement of gold and copper complexes, obtained in our laboratory from phosphorous-based ligands. In the first part, we will develop a new system for the N-arylation of pyrazoles from a copper complexe coordinated by a new hybrid phosphinoalkene ligand. In the second part, coordination properties of gold to different ferrocenic polyphosphine will be studied. Several new innovative complexes will be isolated, and could be used in future catalytic or luminescent studies.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-06-23 |