6533b862fe1ef96bd12c74c5

RESEARCH PRODUCT

Controlling the dimensionality of oxalate-based bimetallic complexes: The ferromagnetic chain {[K(18-crown-6)][Mn(bpy)Cr(ox)3]}∞(18-crown-6=C12H24O6, , bpy=C10H8N2)

Eugenio CoronadoCarlos Marti-gastaldoJosé R. Galán Mascarós

subject

chemistry.chemical_classificationChemistryStereochemistry18-Crown-6Cationic polymerizationOxalateCoordination complexInorganic Chemistrychemistry.chemical_compoundCrystallographyFerromagnetismChain (algebraic topology)Materials ChemistryOrthorhombic crystal systemPhysical and Theoretical ChemistryBimetallic strip

description

Abstract The bimetallic ferromagnetic chain {[K(18-crown-6)][Mn(bpy)Cr(ox)3]}∞ (1) has been synthesized and characterized. It crystallizes in the orthorhombic chiral space group P212121 [a = 9.0510(2) A, b = 14.4710(3) A, c = 26.8660(8) A, V = 3510.97(1) A3, Z = 2]. Compound 1 is made up by anionic [Mn(bpy)Cr(ox)3]− 1D chains and cationic [K(18-crown-6)]+ complexes. The magnetic exchange within the chain is ferromagnetic [J = +7.8(7) cm−1]. In the solid state, the ferromagnetic chains are well isolated magnetically and no long range magnetic ordering has been observed above 2 K.

yearjournalcountryeditionlanguage
2007-06-01Polyhedron
https://doi.org/10.1016/j.poly.2006.10.024