6533b862fe1ef96bd12c7605

RESEARCH PRODUCT

Linkage isomerism in the metal complex hexa(thiocyanato)rhenate(IV): Synthesis and crystal structure of (NBu4)2[Re(NCS)6] and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)]

Ricardo GonzálezCarlos KremerGiovanni De MunnoJuan FausDonatella ArmentanoRaúl ChiozzoneNatalia Barboza

subject

ThiocyanateStereochemistryCrystal structureHEXAInorganic ChemistryMetalCrystallographychemistry.chemical_compoundchemistryvisual_artMaterials Chemistryvisual_art.visual_art_mediumDimethylformamidePhysical and Theoretical ChemistryLinkage isomerism

description

Abstract The linkage isomers [Re(NCS)6]2− and [Re(NCS)5(SCN)]2− are obtained by the reaction of [ReBr6]2− with NCS− in dimethylformamide. Some differences in the chemical behavior allowed their separation and structural characterization in the form of (NBu4)2[Re(NCS)6] (1) and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)] (2), respectively (Bu = n-C4H9 and Me2phen = 2,9-dimethyl-1,10-phenanthroline).

yearjournalcountryeditionlanguage
2008-06-01Inorganica Chimica Acta
https://doi.org/10.1016/j.ica.2008.01.017