6533b862fe1ef96bd12c76bd
RESEARCH PRODUCT
Variation of extent of reaction in closed chemical equilibrium when changing the temperature at constant volume
Joan Josep Solaz Portoléssubject
Physicschemical equilibriumInfinitesimalThermodynamicsGeneral ChemistryLaws of thermodynamicsLe Chatelier's principlelcsh:ChemistryLe Chatelier's principleVolume (thermodynamics)lcsh:QD1-999Extent of reactionChemical equilibriumConstant (mathematics)extent of reactiondescription
In this paper it is presented a thermodynamic analysis that aims to find the mathematical expression of the variation of extent of reaction with the infinitesimal variation in the temperature at constant volume of a chemical equilibrium mixture. The goal of this paper is to establish an alternative approach to avoid both the Le Chatelier's principle and the problems that emerge when trying to apply its qualitative statements. This attempt is based on the laws of thermodynamics.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-01-01 | Química Nova |