6533b862fe1ef96bd12c7748

RESEARCH PRODUCT

Comparison of the crystal structures of 4,4′-bis[3-(4-methylpiperidin-1-yl)prop-1-yn-1-yl]-1,1′-biphenyl and 4,4′-bis[3-(2,2,6,6-tetramethylpiperidin-1-yl)prop-1-yn-1-yl]-1,1′-biphenyl

Peter A. CrooksNarsimha Reddy PenthalaSean ParkinAnqi WanE.k. Fifer

subject

Biphenylcrystal structureCrystallographybiologyStereochemistryCyclohexane conformationGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsRing (chemistry)biology.organism_classificationResearch Communicationschemistry.chemical_compoundbiphenyl ringchemistryQD901-999TetraMoietyGeneral Materials SciencePiperidinepiperidine ringbis-tertiary ammonium analog

description

The crystal structures of the two title compounds display chair conformations of the piperidine rings in their mol­ecules. In compound (I), the biphenyl system has a twisted conformation with a dihedral angle of 26.57 (6)° while in compound (II) the two phenyl rings are exactly coplanar.

yearjournalcountryeditionlanguage
2015-09-01Acta Crystallographica Section E: Crystallographic Communications
10.1107/s2056989015015352http://scripts.iucr.org/cgi-bin/paper?S2056989015015352