6533b86cfe1ef96bd12c8ac9
RESEARCH PRODUCT
Degradation of Lincomycin in aqueous medium: coupling of solar photocatalysis and membrane separation
Elisa I. García-lópezRaffaele MolinariGiuseppe MarcìSixto Malato-rodríguezVincenzo AugugliaroIgnacio MaldonadoLeonardo PalmisanoVittorio Loddosubject
photocatalytic membraneMaterials scienceAqueous solutionMembrane reactorRenewable Energy Sustainability and the Environmentanimal diseasesKineticsbiochemical phenomena metabolism and nutritionbacterial infections and mycosesLincomycinMembrane technologycarbohydrates (lipids)MembraneChemical engineeringPhotocatalysismedicineGeneral Materials ScienceMicrofiltrationPhotocatalysisPhotodegradationmedicine.drugdescription
Abstract The photocatalytic oxidation of a common antibiotic, the lincomycin was carried out in aqueous suspensions of polycrystalline TiO 2 Degussa P25 irradiated by sunlight. In order to improve the performance of the lincomycin degradation a hybrid system consisting of a solar photoreactor with the photocatalyst in suspension coupled with a membrane module, used to confine both photocatalyst and pollutants in the reaction environment, was tested. A preliminary study was carried out in order to determine some kinetics parameters of the drug photodegradation. The influence of initial substrate concentration on the lincomycin photooxidation rate was investigated. The photooxidation rate follows a pseudo-first order kinetics with respect to the lincomycin concentration under the used experimental conditions. The presence of the membrane reactor allows the catalyst separation and to operate in continuous mode as the membranes rejection for lincomycin and its oxidation products was quite high.
year | journal | country | edition | language |
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2005-10-01 |