A Novel Ionic Exchange Membrane Crystallizer to Recover Magnesium Hydroxide from Seawater and Industrial Brines

6533b86cfe1ef96bd12c8c2b

RESEARCH PRODUCT

A Novel Ionic Exchange Membrane Crystallizer to Recover Magnesium Hydroxide from Seawater and Industrial Brines

Marian Turek Alessandro Tamburini F. Vassallo Giorgio Micale Andrea Cipollina Daniele La Corte

subject

Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi Chimici brine valorisation Inorganic chemistry Ionic bonding chemistry.chemical_element Filtration and Separation 02 engineering and technology lcsh:Chemical technology Article law.invention membrane crystallizer 020401 chemical engineering law Chemical Engineering (miscellaneous)lcsh:TP1-1185 critical raw material lcsh:Chemical engineering 0204 chemical engineering Crystallization wastewater Ion exchange Chemistry Magnesium Process Chemistry and Technology lcsh:TP155-156 bittern Contamination 021001 nanoscience & nanotechnology 6. Clean water Membrane Brine Seawater 0210 nano-technology

description

A novel technology, the ion exchange membrane crystallizer (CrIEM), that combines reactive and membrane crystallization, was investigated in order to recover high purity magnesium hydroxide from multi-component artificial and natural solutions. In particular, in a CrIEM reactor, the presence of an anion exchange membrane (AEM), which separates two-compartment containing a saline solution and an alkaline solution, allows the passage of hydroxyl ions from the alkaline to the saline solution compartment, where crystallization of magnesium hydroxide occurs, yet avoiding a direct mixing between the solutions feeding the reactor. This enables the use of low-cost reactants (e.g., Ca(OH)2) without the risk of co-precipitation of by-products and contamination of the final crystals. An experimental campaign was carried out treating two types of feed solution, namely: (1) a waste industrial brine from the Bolesław Śmiały coal mine in Łaziska G&oacute

year	journal	country	edition	language
2020-10-24	Membranes

10.3390/membranes10110303 http://dx.doi.org/10.3390/membranes10110303

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