6533b86cfe1ef96bd12c8d47

RESEARCH PRODUCT

Meniscus coated high open-circuit voltage bi-layer solar cells

Martijn LenesOlga MalinkiewiczHicham BrineHenk J. Bolink

subject

Materials scienceFullereneOrganic solar cellBand gapGeneral Chemical Engineering02 engineering and technologyengineering.material010402 general chemistry01 natural sciences7. Clean energychemistry.chemical_compoundOpticsCoatingCyaninebusiness.industryOpen-circuit voltageHybrid solar cellGeneral Chemistry021001 nanoscience & nanotechnologyAcceptor0104 chemical scienceschemistryengineeringOptoelectronicsMeniscus0210 nano-technologybusiness

description

Neat bi-layer solar cells of a fullerene acceptor and a cyanine dye donor were prepared using meniscus coating. Meniscus coating is very material efficient and leads to high quality pinhole-free films. The cells exhibit high open circuit voltages of 1 volt, only 0.8 eV below the band gap of the cyanine dye. This is one of the smallest differences reported for organic solar cells and illustrates an almost optimal donor-acceptor energy level alignment.

https://doi.org/10.1039/c2ra20075a