6533b86dfe1ef96bd12c95d4
RESEARCH PRODUCT
Strong donor–acceptor couplings in a special pair-antenna model
Mikhail A. FilatovPierre D. HarveyPierre D. HarveyFrédéric LaquaiDaniel FortinRoger Guilardsubject
ChemistryEnergy transferMetals and Alloyschemistry.chemical_elementFree baseCharge (physics)General ChemistryZincPhotochemistryMolecular physicsAcceptorCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsExcited stateMaterials ChemistryCeramics and CompositesAntenna (radio)Donor acceptordescription
A special pair model composed of two cofacial zinc porphyrins (acceptor) linked to a free base (donor) acts as an energy transfer dyad. Despite the absence of conjugation, ππ*/charge transfer excited states and ultrafast energy transfer (∼5 ps) are noted.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-11-05 | Chemical Communications |