6533b86dfe1ef96bd12c9644

RESEARCH PRODUCT

Effect of nano zinc oxide as UV stabilizer on the weathering performance of wood-polyethylene composite

Davood RasouliMohammad Reza M. FarahaniMehdi TajvidiMehdi FaezipourFrancesco Paolo La MantiaNadka Tzankova Dintcheva

subject

Materials Chemistry2506 Metals and AlloysMaterials sciencePolymers and PlasticsWeatheringComposite numberchemistry.chemical_elementCompression moldingCondensed Matter Physic02 engineering and technologyZinc010402 general chemistry01 natural sciencesContact anglechemistry.chemical_compoundUV absorbentUltimate tensile strengthMaterials ChemistryMechanics of MaterialComposite materialPolymers and PlasticPolyethylene021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesNano-zinc oxidechemistryMechanics of MaterialsPhotocatalysisHigh-density polyethylene0210 nano-technologyWood-HDPE composite

description

Abstract In this study, the effect of using nano-sized zinc oxide (ZnO) particles on the enhancement if the degradation resistance of wood-high density polyethylene (HDPE) composite was investigated through artificial weathering. Samples with different amounts of ZnO mixing ratio (0, 1, 2, and 4 wt%) were manufactured using an internal mixer followed by compression molding. The prepared samples were then exposed to the artificial weathering process in a QUV weatherometer. The weathering behavior of samples was characterized using tensile strength, contact angle analysis, colorimetry, ATR-FTIR spectroscopy and FE-SEM. The results indicated that the amount of surfaces crack, tensile strength loss and contact angle changes decreased as a function of ZnO addition, while lightness changes were not affected. Analysis of the functional groups at the composite surface by ATR-FTIR showed that the incorporation of nano-sized ZnO particles in the composite formulation changed the degradation mechanism of composite to photocatalytic reactions, leading to the production of high levels of zinc carboxylate in the structure of weathered composite.

https://doi.org/10.1016/j.polymdegradstab.2016.08.004