Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosphate)

6533b86dfe1ef96bd12c96ca

RESEARCH PRODUCT

Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosphate)

Kateryna Znovjyak Matti Haukka Igor O. Fritsky Iryna A Golenya Tatiana Yu. Sliva

subject

crystal structure Crystal structure 010402 general chemistry 01 natural sciences Medicinal chemistry Ion Research Communications lcsh:Chemistry chemistry.chemical_compound spin crossover Spin crossover Imidazole General Materials Science ta116 010405 organic chemistry Chemistry spin transition General Chemistry kompleksiyhdisteet Condensed Matter Physics HEXA kidetiede Magnetic susceptibility 3. Good health 0104 chemical sciences Bond length lcsh:QD1-999 Amine gas treating

description

The title compound, [Fe(C27H41N10O3)](PF6)2, is an example of an iron(II) spin-crossover compound. In this compound, C⋯F and CH⋯F/O contacts, present between the cations and anions, extend the structure into a three-dimensional supramolecular network.

year	journal	country	edition	language
2019-02-12	Acta Crystallographica Section E: Crystallographic Communications

10.1107/s2056989019001531 http://europepmc.org/articles/PMC6399689

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