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RESEARCH PRODUCT
Reactions of Maleisomides with Alcohols
I. UzulinaAndris ZicmanisChristian GraillatAlain GuyotIgors Klimenkovssubject
chemistry.chemical_classificationPolymers and PlasticsDouble bondMaleic acidCationic polymerizationEmulsion polymerizationSurfaces Coatings and FilmsStyrenechemistry.chemical_compoundchemistryAmideCritical micelle concentrationPolymer chemistryCopolymerOrganic chemistryPhysical and Theoretical Chemistrydescription
Abstract New surfactants (surfmers) with various amide and ester groups next to C˭C double bonds have been obtained. Maleic acid amidesters (AE) with different hydrophobic groups at the nitrogen atom and hydrophilic substituents at oxygen atoms were synthesized starting with maleic isoimides. 1H KMR and IR spectra were used for their characterization. Some were further characterized for their critical micellar concentration (CMC). A few cationic and zwitterionic surfmers were also prepared from isoimide precursors and characterized. All these surfmers were applied in batch emulsion polymerization of styrene, and in core‐shell seeded copolymerization of styrene and butylacrylate to give latexes with better stability than analogous compounds prepared from hemiesters (HE) of maleic acid.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-12-31 | Journal of Dispersion Science and Technology |