6533b86dfe1ef96bd12c9e83

RESEARCH PRODUCT

Raman spectroscopic study of some lead phosphate glasses with tungsten ions

Dana Alina MagdasGrigore DamianI. ArdeleanL. NasdalaOnuc Cozar

subject

Lead phosphateChemistryInorganic chemistryAnalytical chemistrychemistry.chemical_elementTungstenCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsIonPhosphate glasssymbols.namesakeChemical bondMolecular vibrationMaterials ChemistryCeramics and CompositessymbolsRaman spectroscopyChemical composition

description

Abstract The structure of x WO 3  · (100 −  x )[2P 2 O 5  · PbO] glass system with 0 ⩽  x  ⩽ 50 mol% was investigated by Raman spectroscopy. The characteristic bands of these glasses due to the stretching and bending vibrations were identified and analyzed by the increasing of WO 3 content. This fact allowed us to identify the specific structural units which appear in these glasses and thus to point out the network modifier role of tungsten oxide for low concentrations and its former role at high concentrations.

https://doi.org/10.1016/j.jnoncrysol.2006.03.066