6533b86dfe1ef96bd12ca7f2

RESEARCH PRODUCT

Alternating Chain Magnetism in Catena-μ-Oxo-Hemiporphyrazinatoiron(IV), The First μ-Oxo Linear Chain Complex Of Iron

Philipp GütlichPhilipp GütlichWilliam E. HatfieldWilliam E. HatfieldArmin DatzJoachim SträhleLeonard W. Ter HaarLeonard W. Ter HaarWolfgang HillerMichael Hanack

subject

CrystallographyMagnetismStereochemistryChemistryMössbauer spectroscopyAlternation (geometry)

description

Abstract X-ray studies, Mossbauer, and magnetism show FeOHp to be an antiferromagneticaly coupled alternating chain with J = -133 cm−1, g = 2.3 and an alternation parameter of 0.4.

https://doi.org/10.1080/00268948408072080