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RESEARCH PRODUCT
Reduction of [(C 5 Me 5 ) 2 Mo 2 O 5 ] and [(C 5 Me 5 ) 2 Mo 2 O 4 ] in Methanol/Water/Trifluoroacetate Solutions Investigated by Combined On‐Line Electrochemistry/Electrospray‐Ionization Mass Spectrometry
Jenny GunAlexandre ModestovOvadia LevRinaldo Polisubject
Electrospray ionization010401 analytical chemistryAnalytical chemistrychemistry.chemical_element010402 general chemistryMass spectrometryElectrochemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryMolybdenumTrifluoroacetic acidMethanolMethanol waterdescription
Complexes [Cp*2Mo2O5 ]( Cp* =η 5 -C5Me5) and [Cp*2Mo2O4] were investigated by combined on-line electrochemical (EC) reduction and electrospray-ionization mass spectrometry (ESI-MS) techniques in a trifluoroacetic acid buffered water/ methanol solution. The reduction products at the larger negative potentials are identical for both compounds. The studies reveal the existence of a wide range of previously unknown di- and trinuclear Mo V ,M o IV ,M o III , and mixed-val
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-06-01 | European Journal of Inorganic Chemistry |