6533b86efe1ef96bd12cb37b

RESEARCH PRODUCT

Anion-controlled formation of an aminal-(bis)imine Fe(ii)-complex.

Kari RissanenFilip TopićPrasenjit MalChandan Giri

subject

Inorganic Chemistrychemistry.chemical_compoundChemistryPolymer chemistryIminemedicineAminalOrganic chemistryta116ChlorideTrifluoromethanesulfonatemedicine.drugIon

description

In the presence of triflate as the counter anion, 1,2-diaminobenzene and 2-formylpyridine self-sort with iron(II) to a low-spin [Fe(L1)](OTf)2 complex in which both aminal and imine moieties coexist simultaneously, while under similar conditions the chloride anion leads to a high-spin [Fe(L2)Cl2] complex.

yearjournalcountryeditionlanguage
2014-09-17Dalton transactions (Cambridge, England : 2003)
10.1039/c4dt02180khttps://pubmed.ncbi.nlm.nih.gov/25226268