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RESEARCH PRODUCT

ChemInform Abstract: In situ DRIFT Spectroscopic Investigation on the Chemical Evolution of Zinc Phosphate Acid-Base Cement.

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Diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy has been used to follow the chemical evolution of zinc phosphate acid−base cement (ZPC), which has been prepared from unmodified, as well as from aluminum- and zinc-modified orthophosphoric acid. For the first time, amorphous dizinc cyclotetraphosphate octahydrate, Zn2P4O12·8H2O, although hydrolytically instable, has been observed as precursor phase prior to crystallization of α-hopeite, α-Zn3(PO4)2·4H2O, in both systems. Within minutes from onset of mixing the infrared spectrum of unmodified ZPC is dominated by the characteristic vibrations of α-hopeite, due to matrix crystallization. Setting of modified ZPC is strongly affected by the presence of initially soluble aluminophosphate complexes, which form a hydrogel upon neutralization. Steric hindrance plays the key role in the sluggish crystallization kinetics of modified ZPC. The high compressive strength of modified ZPC is brought about by a condensed anion structure. Conceptionally, s...