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RESEARCH PRODUCT
2,4,6-Tris(1-oxo-2-pyridylsulfanylmethyl)mesitylene methanol solvate
Dieter SchollmeyerB. Ravindran Durai NayagamSamuel Robinson JebasC. Ravi Samuelrajsubject
TrisHydrogen bondGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsRing (chemistry)Organic PapersCrystallographychemistry.chemical_compoundchemistryPerpendicularGeneral Materials ScienceMethanolMesitylenedescription
In the title compound, C(27)H(27)N(3)O(3)S(3)·CH(4)O, the dihedral angles formed by the mesitylene ring with the three oxopyridyl rings are 89.6 (1), 75.5 (1) and 80.69 (1)°, indicating that all three are nearly perpendicular to the mesitylene ring. Intra-molecular C-H⋯S hydrogen bonds generate S(6) ring motifs. The crystal structure is stabilized by intra-molecular C-H⋯S and inter-molecular C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-05-10 | Acta Crystallographica Section E: Structure Reports Online |