6533b86ffe1ef96bd12cdb5a

RESEARCH PRODUCT

Influence of dissolved humic material and ionic strength on C8 extraction of pesticides from water

Guillermina FontBeatriz JiménezJuan Carlos Moltó

subject

chemistry.chemical_classificationAqueous solutionChromatographyElutionChemistrySodiumOrganic ChemistryClinical BiochemistryExtraction (chemistry)chemistry.chemical_elementBiochemistryAnalytical ChemistryMatrix (chemical analysis)Ionic strengthHumic acidSolid phase extraction

description

A mixture of twelve intermediate polarity pesticides, mostly carbamate-type, have been chromatographied on an octadecyl-silica bonded-phase column using acetonitrile-water gradient mobile phase and UV detection. Pesticides were extracted from aqueous matrix by solid-phase extraction. The extraction system consisted of a glass microcolumn containing octyl-silica solidphase conditioned with methanol and water. The elution was by acetonitrile-dichloromethane (50:50). Studies of extraction factors like volume of sample, addition of 10% sodium chloride and presence of dissolved humic material are investigated.

https://doi.org/10.1007/bf02688046