6533b870fe1ef96bd12cf02e

RESEARCH PRODUCT

ortho-Metalated Dirhodium(II) Catalysts Immobilized on a Polymeric Cross-Linked Support by Copolymerization. Study of their Catalytic Activity in the Asymmetric Cyclopropanation of Styrene with Ethyl Diazoacetate

Ma Angeles ÚBedaJulio LloretMercedes SanaúFrancisco EstevanMaria Stern

subject

Inorganic Chemistrychemistry.chemical_compoundChromatographyEthyl diazoacetateChemistryCyclopropanationOrganic ChemistryPolymer chemistryCopolymerPhysical and Theoretical ChemistryPhosphineCatalysisStyrene

description

Chiral ortho-metalated dirhodium(II) compounds containing the phosphine P(p-CH2═CHC6H4)3 have been efficiently immobilized by radical copolymerization with styrene and 1,4-divinylbenzene. Their cat...

https://doi.org/10.1021/om700612m